MS Final Examination Seminar – Steven De Alwis

Date/Time
Date(s) - 6 Aug 2020
1:00 PM - 2:00 PM

Location

MS Final Examination Seminar

Steven De Alwis

https://iastate.webex.com/meet/sdealwis


Title

Hydrodynamic Cavitation for Scalable Exfoliation of Few Layered Graphene Nanosheets

Abstract

A simple method for protein assisted scalable exfoliation of biocompatible few layered graphene (FLG) nano-sheets is developed using hydrodynamic cavitation. Hydrodynamic cavitation is used for the exfoliation. Unlike acoustic cavitation, the primary way of bubble collapse in hydrodynamic cavitation is caused laterally, thereby separating two adjacent flakes by a shear effect. The process utilizes a known protein, Bovine Serum Albumin (BSA), which acts as an effective exfoliation agent and provides stability by preventing restacking of the graphene layers. Development of potentially scalable biocompatible methods are critical for producing cost-effective non-toxic graphene, enabling numerous possible biomedical and biological applications. A methodical study was performed to identify the effect of time in a novel hydrodynamic cavitation system for graphene exfoliation. The fabricated product was characterized using Raman spectroscopy and Transmission electron microscopy. It was found that with time the number of layers of graphene seem to decrease based on the I2D/IG ratio where at 6 hours the ratio was at 0.307 but along with that disorder in graphene seem to increase based on the ID/Iratio which reached up to .33 from .25 at 4.5 hours. The paper also provides the theoretical and the computational analysis needed to create an optimized cavitation model to potentially improve the graphene yield and fabricate higher quality graphene.

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